Q20 / 90 · JEE Main 2023 (25 Jan Shift 1) · Chemistry

Figure

The correct sequence of reagents for the preparation of Q and R is:

  • Correct answer
    A
    (i) Cr2O3, 770 K, 20 atm; (ii) CrO2Cl2, H3O+; (iii) NaOH; (iv) H3O+
  • B
    (i) CrO2Cl2, H3O+; (ii) Cr2O3, 770 K, 20 atm; (iii) NaOH; (iv) H3O+
  • C
    (i) KMnO4, OH-; (ii) Mo2O3, Δ; (iii) NaOH; (iv) H3O+
  • D
    (i) Mo2O3, Δ; (ii) CrO2Cl2, H3O+; (iii) NaOH; (iv) H3O+

Solution

It is a sequence of reactions where heptane is oxidised to methyl benzene, further oxidised to benzaldehyde, and finally cannizzaro reaction occurs to give the desired product.

Figure 

Hence, the correct answer is option: 'A'.

Relevant Questions