Q16 / 75 · JEE Main 2025 (24 Jan Shift 1) · Chemistry

Following are the four molecules "P", "Q", "R" and "S". Which one among the four molecules will react with $\mathrm{H}-\mathrm{Br}_{(\mathrm{aq})}$ at the fastest rate? Figure

  • A
    R
  • B
    P
  • Correct answer
    C
    Q
  • D
    S

Solution

Addition of $\mathrm{H}-\mathrm{Br}_{(\mathrm{aq})}$ to alkene follows electrophilic addition mechanism. In the rate determining step a carbocation intermediate is formed. Among $\mathrm{P}, \mathrm{Q}$, R \& S compound Q will form most stable carbocation intermediate since it is resonance stabilized. Figure

Hence, the correct answer is option: 'C'.

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