Q15 / 75 · JEE Main 2025 (29 Jan Shift 2) · Chemistry

Given below are two statements : Statement (I) : On nitration of m-xylene with $\mathrm{HNO}_3, \mathrm{H}_2 \mathrm{SO}_4$ followed by oxidation, 4-nitrobenzene-1,3-dicarboxylic acid is obtained as the major product. Statement (II) : $-\mathrm{CH}_3$ group is o/p-directing while $-\mathrm{NO}_2$ group is m-directing group. In the light of the above statements, choose the correct answer from the options given below :

  • A
    Both Statement I and Statement II are false
  • B
    Statement I is false but Statement II is true
  • C
    Statement I is true but Statement II is false
  • Correct answer
    D
    Both Statement I and Statement II are true

Solution

Statement - I Figure
Statement-II $-\mathrm{CH}_3$ group is o/p directing while $-\mathrm{NO}_2$ group is meta directing.

Hence, the correct answer is option: 'D'.

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