Q15 / 75 · JEE Main 2025 (29 Jan Shift 2) · Chemistry
Given below are two statements :
Statement (I) : On nitration of m-xylene with $\mathrm{HNO}_3, \mathrm{H}_2 \mathrm{SO}_4$ followed by oxidation, 4-nitrobenzene-1,3-dicarboxylic acid is obtained as the major product.
Statement (II) : $-\mathrm{CH}_3$ group is o/p-directing while $-\mathrm{NO}_2$ group is m-directing group.
In the light of the above statements, choose the correct answer from the options given below :
- ABoth Statement I and Statement II are false
- BStatement I is false but Statement II is true
- CStatement I is true but Statement II is false
- Correct answerDBoth Statement I and Statement II are true
Solution
Statement - I

Statement-II $-\mathrm{CH}_3$ group is o/p directing while $-\mathrm{NO}_2$ group is meta directing.

Statement-II $-\mathrm{CH}_3$ group is o/p directing while $-\mathrm{NO}_2$ group is meta directing.
Hence, the correct answer is option: 'D'.