Q11 / 120 · VITEEE 2010 · Chemistry

When p-nitrobromobenzene reacts with sodium ethoxide, the product obtained is

  • A
    $\mathrm{p}$-nitroanisole
  • B
    ethyl phenyl ether particles and forms $_{76} \mathrm{Y}^{235}$.
  • Correct answer
    C
    $\mathrm{p}$-nitrophenetole
  • D
    no rcan.

Solution

Commonly aryl halides do not take part in Williamson's synthesis, due to their high stability but due to the presence of strong electron withdrawing group like $-\mathrm{NO}_{2}$ makes the $\mathrm{C}-\mathrm{X}$ bond weaker and substitution of -Br takes place by $-\mathrm{OR}$. Figure

Hence, the correct answer is option: 'C'.

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