Q10 / 110 · VITEEE 2024 · Chemistry

Which of the following compounds on reaction with $\mathrm{CH}_3 \mathrm{MgBr}$ will give a tertiary alcohol?

  • A
    $\mathrm{C}_6 \mathrm{H}_5 \mathrm{CHO}$
  • Correct answer
    B
    $\mathrm{C}_2 \mathrm{H}_5 \mathrm{CO}_2 \mathrm{C}_2 \mathrm{H}_5$
  • C
    $\mathrm{C}_2 \mathrm{H}_5 \mathrm{COOH}$
  • D
    Figure

Solution

Esters react with Grignard reagent to form tertiary $\left(3^{\circ}\right)$ alcohols. The complete reaction is given as follows Figure

Hence, the correct answer is option: 'B'.

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