Q36 / 150 · MHT CET 2026 (15 April Shift 1) · Chemistry
When a mixture of two different alkyl halides reacts with metallic sodium in dry ether, the formation of a possible number of alkanes are-
- ATwo
- Correct answerBThree
- CFour
- DFive
Solution
Let the two different alkyl halides be $R-X$ and $R'-X$.
When this mixture reacts with metallic sodium in dry ether (Wurtz reaction), three types of coupling reactions take place.
$R-X + 2Na + X-R \rightarrow R-R + 2NaX$
$R'-X + 2Na + X-R' \rightarrow R'-R' + 2NaX$
$R-X + 2Na + X-R' \rightarrow R-R' + 2NaX$
Thus, a total of three different alkanes are formed.
Answer: Three
When this mixture reacts with metallic sodium in dry ether (Wurtz reaction), three types of coupling reactions take place.
$R-X + 2Na + X-R \rightarrow R-R + 2NaX$
$R'-X + 2Na + X-R' \rightarrow R'-R' + 2NaX$
$R-X + 2Na + X-R' \rightarrow R-R' + 2NaX$
Thus, a total of three different alkanes are formed.
Answer: Three
Hence, the correct answer is option: 'B'.