Q36 / 150 · MHT CET 2026 (15 April Shift 1) · Chemistry

When a mixture of two different alkyl halides reacts with metallic sodium in dry ether, the formation of a possible number of alkanes are-

  • A
    Two
  • Correct answer
    B
    Three
  • C
    Four
  • D
    Five

Solution

Let the two different alkyl halides be $R-X$ and $R'-X$.

When this mixture reacts with metallic sodium in dry ether (Wurtz reaction), three types of coupling reactions take place.

$R-X + 2Na + X-R \rightarrow R-R + 2NaX$

$R'-X + 2Na + X-R' \rightarrow R'-R' + 2NaX$

$R-X + 2Na + X-R' \rightarrow R-R' + 2NaX$

Thus, a total of three different alkanes are formed.

Answer: Three

Hence, the correct answer is option: 'B'.

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