Q12 / 90 · JEE Main 2022 (26 Jun Shift 2) · Chemistry

Toluene can be easily converted into benzaldehyde by which of the following reagents?

  • A
    CrO3 /acetic acid, H3O+
  • Correct answer
    B
    CrO3 /acetic anhydride, H3O+
  • C
    KMnO4/HCl,H3O+
  • D
    CO, HCl, Anhyd. AlCl3

Solution

Toluene is oxidised to benzaldehyde in presence of CrO3 /acetic anhydride, H3O+

Toluene is converted to benzylidene diacetate and hydrolysis reaction of benzylidene diacetate gives benzaldehyde.

Figure

Hence, the correct answer is option: 'B'.

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