Q8 / 51 · JEE Advanced 2023 (Paper 1) · Chemistry

The stoichiometric reaction of 516 g of dimethyldichlorosilane with water results in a tetrameric cyclic product X in 75% yield. The weight (in g) of X obtained is ____________

[Use, molar mass gmol-1:H=1,C=12,O=16,Si=28,Cl=35.5]

 

Correct answer: 222

Solution

The dimethyldichlorosilane is CH32SiCl2. The molecular mass is 129 u.

Number of moles of dimethyldichlorosilane initially taken =516129= 4moles

Figure

Applying POAC on Si atom

Moles of tetrameric cyclic product formed =44×75100=0.75 moles

Molar mass of product formed =296 g/moles

The mass of product formed =296×0.75=222 g

Hence, the correct answer is 222.

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