Q12 / 54 · JEE Advanced 2017 (Paper 2) · Chemistry

Among the following, the correct statement(s) is(are)

  • Correct answer
    A
    AlCH33 has the three-centre two-electron bonds in its dimeric structure
  • B
    AlCl3 has the three-centre two-electron bonds in its dimeric structure
  • Correct answer
    C
    BH3 has the three-centre two-electron bonds in its dimeric structure
  • Correct answer
    D
    The Lewis acidity of BCl3 is greater than that of AlCl3

Solution

(i)  Figure

(ii)  Figure

(iii) Figure

(iv)  Lewis acidic strength decreases down the group. The decrease in acid strength occurs because as size increases, the attraction between the incoming electron pair and the nucleus weakens.

Hence Lewis acidic strength of BCl3 is more than AlCl3.

 

Hence, the correct answer is options: 'A', 'C', 'D'.

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