Q14 / 120 · JEE Advanced 2006 · Chemistry

The species present in solution when $\mathrm{CO}_2$ is dissolved in water are

  • Correct answer
    A
    $\mathrm{CO}_2, \mathrm{H}_2 \mathrm{CO}_3, \mathrm{HCO}_3^{-}, \mathrm{CO}_3^{2-}$
  • B
    $\mathrm{H}_2 \mathrm{CO}_3, \mathrm{CO}_3^{2-}$
  • C
    $\mathrm{CO}_3^{2-}, \mathrm{HCO}_3^{-}$
  • D
    $\mathrm{CO}_2, \mathrm{H}_2 \mathrm{CO}_3$

Solution

When $\mathrm{CO}_2$ is dissolved in water, therefore it forms dibasic carbonic acid, which gives $\mathrm{HCO}_3^{-}$ and $\mathrm{CO}_3^{2-}$ ions on ionisation. Hence in solution $\mathrm{CO}_2, \mathrm{H}_2 \mathrm{CO}_3, \mathrm{HCO}_3^{-}$and $\mathrm{CO}_3^{2-}$ are present. Figure

Hence, the correct answer is option: 'A'.

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