Q13 / 180 · KCET 2011 · Chemistry

The rms velocity of hydrogen is $\sqrt{7}$ times the rms velocity of nitrogen. If $T$ is the temperature of the gas, which of the following is true?

  • A
    $T_{\mathrm{H}_{2}}=\sqrt{7} T_{\mathrm{N}_{2}}$
  • B
    $T_{\mathrm{N}_{2}}=T_{\mathrm{H}_{2}}$
  • C
    $T_{\mathrm{N}_{2}}=\sqrt{7} T_{\mathrm{H}_{2}}$
  • Correct answer
    D
    $T_{\mathrm{N}_{2}}=2 T_{\mathrm{H}_{2}}$

Solution

$$ \begin{aligned} \frac{C_{\mathrm{H}_{2}}}{C_{\mathrm{N}_{2}}}=\sqrt{7} &=\sqrt{\frac{T_{\mathrm{H}_{2}} \times 28}{2 \times T_{\mathrm{N}_{2}}}} \\ 7 &=\frac{14 T_{\mathrm{H}_{2}}}{T_{\mathrm{N}_{2}}} \\ T_{\mathrm{N}_{2}} &=2 T_{\mathrm{H}_{2}} \end{aligned} $$

Hence, the correct answer is option: 'D'.

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