Q15 / 180 · KCET 2010 · Chemistry

For one mole of an ideal gas, increasing the temperature from $10^{\circ} \mathrm{C}$ to $20^{\circ} \mathrm{C}$

  • A
    increases the average kinetic energy by two times
  • B
    increases the rms velocity by $\sqrt{2}$ times
  • C
    increases the rms velocity by two times
  • Correct answer
    D
    increases both the average kinetic energy and rms velocity, but not significantly

Solution

Given, $\mathrm{T}_{1}=273+10=283 \mathrm{~K}$ $$ \mathrm{T}_{2}=273+20=293 \mathrm{~K} $$ Average $\mathrm{KE}=\frac{3}{2} \mathrm{KT}$ $$ \frac{\left(\mathrm{KE}_{1}\right)}{\left(\mathrm{KE}_{2}\right)}=\frac{283}{293}=0.96 $$ Root mean square (rms) velocity, $$ \mathrm{v}_{\mathrm{rms}}=\sqrt{\frac{3 \mathrm{RT}}{\mathrm{M}}} $$ $$ \begin{aligned} \frac{\mathrm{v}_{(\mathrm{rms})_{1}}}{\mathrm{v}_{(\mathrm{rms})_{2}}} &=\sqrt{\frac{\mathrm{T}_{1}}{\mathrm{~T}_{2}}} \\ &=\sqrt{\frac{283}{293}}=0.98 \end{aligned} $$ Thus, both average kinetic energy and root mean square velocity increase but not significantly when temperature is increased from $10^{\circ} \mathrm{C}$ to $20^{\circ} \mathrm{C}$.

Hence, the correct answer is option: 'D'.

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