Q30 / 220 · NTA Abhyas (NEET) 2020 · Chemistry · Ionic Equilibrium

The pKa of acetic acid and pKb of NH4OH are 4.76 and 4.75, respectively. Calculate the pH of ammonium acetate solution.

  • A
    7.5
  • Correct answer
    B
    7.005
  • C
    7.05
  • D
    7.55

Solution

Acetic acid and NH4OH are weak acid (WA) and weak base (WB) respectively. When they combine a salt of WA and WB i.e., ammonium acetate is formed. So by using hydrolysis equation for salts of WA and WB ,
pH=12(pKw+pKa-pKb)
= 1 2 14+4.76−4.75
=7+0.005=7.005 .

Hence, the correct answer is option: 'B'.

More Ionic Equilibrium Questions