Q29 / 220 · NTA Abhyas (NEET) 2020 · Chemistry · Ionic Equilibrium

A certain buffer solution contains equal concentration of X- and HX. The Kb for X- is 10-10. The pH of the buffer is

  • Correct answer
    A
    4
  • B
    7
  • C
    10
  • D
    14

Solution

X −  +  H 2 O ⇌  OH −  + HX
Kb=[OH-][HX][X-]
HX ⇌  H +  +  X −
Ka=[H+][X-][HX]
∴Ka×Kb=[H+][OH-]=Kw=10-14
Hence Ka=10-4
Now as [X-]=[HX],pH=pKa=4 .

Hence, the correct answer is option: 'A'.

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