Q89 / 200 · NEET 2024 (Re-NEET) · Chemistry

The following reaction method Figure
is not suitable for the preparation of the corresponding haloarene products, due to high reactivity of halogen, when X is :

  • Correct answer
    A
    F
  • B
    I
  • C
    Cl
  • D
    Br

Solution

- Aryl chlorides and bromides can easily be prepared by electrophilic substitution of arenes (toluene) with $\mathrm{Cl}_2$ and $\mathrm{Br}_2$ respectively in the presence of Lewis acid catalyst ( Fe in dark). - Reaction with $\mathrm{I}_2$ is reversible and requires the presence of oxidising agent. - Corresponding fluoroarene is not prepared by this method due to high reactivity of fluorine. Hence, ' X ' is $F$.

Hence, the correct answer is option: 'A'.

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