Q89 / 200 · NEET 2024 (Re-NEET) · Chemistry
The following reaction method

is not suitable for the preparation of the corresponding haloarene products, due to high reactivity of halogen, when X is :

is not suitable for the preparation of the corresponding haloarene products, due to high reactivity of halogen, when X is :
- Correct answerAF
- BI
- CCl
- DBr
Solution
- Aryl chlorides and bromides can easily be prepared by electrophilic substitution of arenes (toluene) with $\mathrm{Cl}_2$ and $\mathrm{Br}_2$ respectively in the presence of Lewis acid catalyst ( Fe in dark).
- Reaction with $\mathrm{I}_2$ is reversible and requires the presence of oxidising agent.
- Corresponding fluoroarene is not prepared by this method due to high reactivity of fluorine. Hence, ' X ' is $F$.
Hence, the correct answer is option: 'A'.