Q90 / 200 · NEET 2024 (Re-NEET) · Chemistry

The alkane that can be oxidized to the corresponding alcohol by $\mathrm{KMnO}_4$ as per the equation Figure
is, when:

  • A
    $\mathrm{R}_1=\mathrm{H} ; \mathrm{R}_2=\mathrm{H} ; \mathrm{R}_3=\mathrm{H}$
  • Correct answer
    B
    $\mathrm{R}_1=\mathrm{CH}_3 ; \mathrm{R}_2=\mathrm{CH}_3 ; \mathrm{R}_3=\mathrm{CH}_3$
  • C
    $\mathrm{R}_1=\mathrm{CH}_3 ; \mathrm{R} 2=\mathrm{H} ; \mathrm{R}_3=\mathrm{H}$
  • D
    $\mathrm{R}_1=\mathrm{CH}_3 ; \mathrm{R}_2=\mathrm{CH}_3 ; \mathrm{R}_3=\mathrm{H}$

Solution

Generally alkanes resist oxidation but alkane with tertiary H atom(s) can be oxidised to corresponding alcohols by $\mathrm{KMnO}_4$ Figure
$\therefore \mathrm{R}_1 \Rightarrow \mathrm{CH}_3 \quad \mathrm{R}_2 \Rightarrow \mathrm{CH}_3 \quad \mathrm{R}_3 \Rightarrow \mathrm{CH}_3$

Hence, the correct answer is option: 'B'.

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