Q19 / 90 · JEE Main 2023 (06 Apr Shift 2) · Chemistry

Structures of BeCl2 in solid state, vapour phase and at very high temperature respectively are:

  • A
    Monomeric, Dimeric, Polymeric
  • B
    Dimeric, Polymeric, Monomeric
  • C
    Polymeric, Monomeric, Dimeric
  • Correct answer
    D
    Polymeric, Dimeric, Monomeric

Solution

BeCl2 is dimeric in vapour phase. The coordination number of beryllium is 3.

Figure

BeCl2 is monomeric at high temperature. The coordination number of beryllium is 2.

Figure

BeCl2 is polymeric in solid state. The coordination number of beryllium is 4.

Figure

Hence, the correct answer is option: 'D'.

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