Q12 / 90 · JEE Main 2024 (08 Apr Shift 1) · Chemistry
Give below are two statements: One is labelled as Assertion \(\mathrm{A}\) and the other is labelled as Reason R:
Assertion A: The stability order of +1 oxidation state of Ga, In and T1 is \(\mathrm{Ga} < \mathrm{In} < \) T1.
Reason R: The inert pair effect stabilizes the lower oxidation state down the group.
In the light of the above statements, choose the correct answer from the options given below:
- A\(\mathrm{A}\) is true but \(\mathrm{R}\) is false.
- B\(\mathrm{A}\) is false but \(\mathrm{R}\) is true.
- Correct answerCBoth \(\mathrm{A}\) and \(\mathrm{R}\) are true and \(\mathrm{R}\) is the correct explanation of \(\mathrm{A}\).
- DBoth \(\mathrm{A}\) and \(\mathrm{R}\) are true but \(\mathrm{R}\) is NOT the correct explanation of \(\mathrm{A}\).
Solution
The relative stability of +1 oxidation state progressively increases for heavier elements due to inert pair effect.
$\therefore$ Stability of $\mathrm{A} \ell^{+1} < \mathrm{Ga}^{+1} < \mathrm{In}^{+1} < \mathrm{T} \ell^{+1}$
Hence, the correct answer is option: 'C'.