Q20 / 150 · MHT CET 2026 (11 April Shift 2) · Chemistry
$200$ mL of ethylene gas and $150$ mL of HCl gas were allowed to react at $1$ bar. Pressure to form gaseous ethyl chloride. What is the work done during the reaction?
- Correct answerA$15$ J
- B$30$ J
- C$150$ J
- D$300$ J
Solution
The balanced chemical equation for the reaction is:
$C_2H_4(g) + HCl(g) \rightarrow C_2H_5Cl(g)$
Initial volumes:
$V_{C_2H_4} = 200$ mL
$V_{HCl} = 150$ mL
Total initial volume $V_i = 200 + 150 = 350$ mL.
Since the reaction occurs at constant pressure and temperature, the volumes of gases are directly proportional to their number of moles. Here, $HCl$ is the limiting reagent.
Volume of $C_2H_4$ reacted = $150$ mL
Volume of $C_2H_4$ remaining = $200 - 150 = 50$ mL
Volume of $C_2H_5Cl$ formed = $150$ mL
Total final volume $V_f = 50 + 150 = 200$ mL.
Change in volume $\Delta V = V_f - V_i = 200 - 350 = -150$ mL = $-0.15$ L.
The work done during the reaction at constant pressure is given by:
$W = -P \Delta V$
Substituting the values:
$W = -1 \text{ bar} \times (-0.15 \text{ L}) = 0.15 \text{ L bar}$
Since $1 \text{ L bar} = 100 \text{ J}$, we get:
$W = 0.15 \times 100 \text{ J} = 15 \text{ J}$
Answer: $15$ J
$C_2H_4(g) + HCl(g) \rightarrow C_2H_5Cl(g)$
Initial volumes:
$V_{C_2H_4} = 200$ mL
$V_{HCl} = 150$ mL
Total initial volume $V_i = 200 + 150 = 350$ mL.
Since the reaction occurs at constant pressure and temperature, the volumes of gases are directly proportional to their number of moles. Here, $HCl$ is the limiting reagent.
Volume of $C_2H_4$ reacted = $150$ mL
Volume of $C_2H_4$ remaining = $200 - 150 = 50$ mL
Volume of $C_2H_5Cl$ formed = $150$ mL
Total final volume $V_f = 50 + 150 = 200$ mL.
Change in volume $\Delta V = V_f - V_i = 200 - 350 = -150$ mL = $-0.15$ L.
The work done during the reaction at constant pressure is given by:
$W = -P \Delta V$
Substituting the values:
$W = -1 \text{ bar} \times (-0.15 \text{ L}) = 0.15 \text{ L bar}$
Since $1 \text{ L bar} = 100 \text{ J}$, we get:
$W = 0.15 \times 100 \text{ J} = 15 \text{ J}$
Answer: $15$ J
Hence, the correct answer is option: 'A'.