Q78 / 200 · NEET 2004 · Chemistry

$\mathrm{CN}^{-}$is strong field ligand. This is due to the fact that :

  • A
    it carries negative charge
  • Correct answer
    B
    it is a pseudohalide
  • C
    it can accept electrons from metal species
  • D
    it form high spin complexes with metal species

Solution

Cyanide ion is strong field ligand because it is a pseudohalide ion. Pseudohalide ions are stronger coordinating ligand \& they have the ability to form $\sigma$ bond (from the pseudohalide to the metal) and $\pi$ bond (from the metal to pseudohalide). Related Theory A pseudohalide is an anion which has similar properties to a halogen, but not a real halogen. Pseudohalogens are polyatomic analogues of halogens, or also called 'fake' halogens, whose properties resemble that of true halogens.

Hence, the correct answer is option: 'B'.

Relevant Questions