Q86 / 200 · NEET 2022 (Phase 2) · Chemistry

Given below are two statements: Statement I: $\mathrm{Cr}^{2+}$ is oxidising and $\mathrm{Mn}^{3+}$ is reducing in nature. Statement II: $\mathrm{Sc}^{3+}$ compounds are repelled by the applied magnetic field. In the light of the above statements, choose the most appropriate answer from the options given below:

  • A
    Both Statement I and Statement II are correct
  • B
    Both Statement I and Statement II are incorrect
  • C
    Statement I is correct but Statement II is incorrect
  • Correct answer
    D
    Statement I is incorrect but Statement II is correct

Solution

Figure
Half filled $d$-orbital (more stable) Therefore, $\mathrm{Mn}^{3+}$ acts as an oxidising agent. $\mathrm{Sc}^{3+}$ - [Ar] All elements are paired making it diamagnetic. Hence $\mathrm{Sc}^{3+}$ compounds are repelled when placed in an external magnetic field.

Hence, the correct answer is option: 'D'.

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