Q44 / 102 · NTA Abhyas (JEE Main) 2020 · Chemistry · Ionic Equilibrium

In a buffer solution having equal concentrations of B- and HB the value of Kb for B- is 10-9 . The pH of buffer solution is

  • A
    9
  • Correct answer
    B
    5
  • C
    4
  • D
    6

Solution

For acidic buffer pH can be find out as follows
pH=pKa+log10[salt][acid]
As here Kb=10-9
So Ka=10-5
pKa=5
As pH=5+⁡log10[B-][HB]
As [B-]=[HB]
pH=5+log 1=5 + 0 = 5

Hence, the correct answer is option: 'B'.

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