Q16 / 150 · MHT CET 2026 (15 April Shift 2) · Chemistry

If a 0.4 molal solution of a nonvolatile solute in organic solvent decreases its freezing point by 2.4 K., then the molal depression constant of solvent will be

  • A
    $3.0\ \text{K kg mol}^{-1}$
  • B
    $4.0\ \text{K kg mol}^{-1}$
  • C
    $5.0\ \text{K kg mol}^{-1}$
  • Correct answer
    D
    $6.0\ \text{K kg mol}^{-1}$

Solution

Using the formula for depression in freezing point:

$\Delta T_f = K_f \times m$

Given $\Delta T_f = 2.4$ K and $m = 0.4$ mol kg$^{-1}$.

Substituting the values:

$2.4 = K_f \times 0.4$

$K_f = \dfrac{2.4}{0.4} = 6.0$ K kg mol$^{-1}$

Answer: $6.0\ \text{K kg mol}^{-1}$

Hence, the correct answer is option: 'D'.

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