Q35 / 150 · MHT CET 2026 (19 April Shift 1) · Chemistry

A solution of non volatile solute has boiling point elevation $0.70$ K if $K_b$ for the solvent is $2.44\ \text{K kg mol}^{-1}$. What is the molality of the solution?

  • A
    $3.48$ m
  • B
    $2.86$ m
  • Correct answer
    C
    $0.286$ m
  • D
    $0.0186$ m

Solution

The elevation in boiling point is given by the formula:

$\Delta T_b = K_b \times m$

where $\Delta T_b$ is the boiling point elevation, $K_b$ is the ebullioscopic constant, and $m$ is the molality of the solution.

Given:
$\Delta T_b = 0.70$ K
$K_b = 2.44$ K kg mol$^{-1}$

Substituting the given values into the formula:

$0.70 = 2.44 \times m$

$m = \dfrac{0.70}{2.44}$

$m \approx 0.286$ m

Answer: $0.286$ m

Hence, the correct answer is option: 'C'.

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