Q34 / 150 · MHT CET 2026 (19 April Shift 1) · Chemistry
Identify change in oxidation state of oxidising agent in following redox reaction.
$3\text{H}_3\text{AsO}_{3(aq)} + \text{BrO}_{3(aq)}^- \longrightarrow \text{Br}_{(aq)}^- + 3\text{H}_3\text{AsO}_{4(aq)}$
$3\text{H}_3\text{AsO}_{3(aq)} + \text{BrO}_{3(aq)}^- \longrightarrow \text{Br}_{(aq)}^- + 3\text{H}_3\text{AsO}_{4(aq)}$
- A$-1\ \text{to}\ +5$
- Correct answerB$+5\ \text{to}\ -1$
- C$+3\ \text{to}\ +5$
- D$+5\ \text{to}\ +3$
Solution
The given reaction is $3\text{H}_3\text{AsO}_{3(aq)} + \text{BrO}_{3(aq)}^- \longrightarrow \text{Br}_{(aq)}^- + 3\text{H}_3\text{AsO}_{4(aq)}$
Let the oxidation state of As in $\text{H}_3\text{AsO}_3$ be $x$.
$3(+1) + x + 3(-2) = 0 \Rightarrow x = +3$
Let the oxidation state of Br in $\text{BrO}_3^-$ be $y$.
$y + 3(-2) = -1 \Rightarrow y = +5$
Let the oxidation state of As in $\text{H}_3\text{AsO}_4$ be $z$.
$3(+1) + z + 4(-2) = 0 \Rightarrow z = +5$
The oxidation state of Br in $\text{Br}^-$ is $-1$.
The oxidation state of As increases from $+3$ to $+5$, so $\text{H}_3\text{AsO}_3$ undergoes oxidation and acts as a reducing agent.
The oxidation state of Br decreases from $+5$ to $-1$, so $\text{BrO}_3^-$ undergoes reduction and acts as an oxidising agent.
The change in oxidation state of the oxidising agent is $+5$ to $-1$.
Answer: $+5\ \text{to}\ -1$
Let the oxidation state of As in $\text{H}_3\text{AsO}_3$ be $x$.
$3(+1) + x + 3(-2) = 0 \Rightarrow x = +3$
Let the oxidation state of Br in $\text{BrO}_3^-$ be $y$.
$y + 3(-2) = -1 \Rightarrow y = +5$
Let the oxidation state of As in $\text{H}_3\text{AsO}_4$ be $z$.
$3(+1) + z + 4(-2) = 0 \Rightarrow z = +5$
The oxidation state of Br in $\text{Br}^-$ is $-1$.
The oxidation state of As increases from $+3$ to $+5$, so $\text{H}_3\text{AsO}_3$ undergoes oxidation and acts as a reducing agent.
The oxidation state of Br decreases from $+5$ to $-1$, so $\text{BrO}_3^-$ undergoes reduction and acts as an oxidising agent.
The change in oxidation state of the oxidising agent is $+5$ to $-1$.
Answer: $+5\ \text{to}\ -1$
Hence, the correct answer is option: 'B'.