Q51 / 180 · NEET 2017 · Chemistry
A container at contains at pressure and an excess of (neglect the volume of solid ). The volume of the container is now decreased by moving the movable piston fitted in the container. The maximum volume of the container, when the pressure of attains its maximum value, will be:
- Correct answerA
- B
- C
- D
Solution
Max. pressure of Pressure of at equilibrium.
For reaction,
atm = maximum pressure of .
The volume of the container at this stage.
......(i)
Since the container is sealed and the reaction was not earlier at equilibrium
constant
......(ii)
Put equation (ii) in equation (i)
For reaction,
atm = maximum pressure of .
The volume of the container at this stage.
......(i)
Since the container is sealed and the reaction was not earlier at equilibrium
constant
......(ii)
Put equation (ii) in equation (i)
Hence, the correct answer is option: 'A'.