Q51 / 180 · NEET 2017 · Chemistry

A 20 litre container at 400 K contains CO2g at pressure 0.4 atm and an excess of SrO (neglect the volume of solid SrO ). The volume of the container is now decreased by moving the movable piston fitted in the container. The maximum volume of the container, when the pressure of CO2 attains its maximum value, will be:

Given that:SrCO3s⇌SrOs+CO2g, Kp=1.6 atm

  • Correct answer
    A
    5 litre
  • B
    10 litre
  • C
    4 litre
  • D
    2 litre

Solution

Max. pressure of CO2=Pressure of CO2 at equilibrium.

For reaction,

SrCO3s ⇌SrOs+CO2

Kp=PCO2=1.6 atm = maximum pressure of CO2.

The volume of the container at this stage.

V=nRTP ......(i)

Since the container is sealed and the reaction was not earlier at equilibrium

∴  n=constant

n=PVRT=0.4×20RT ......(ii)

Put equation (ii) in equation (i)

V=0.4×20RT RT1.6=5 L

Hence, the correct answer is option: 'A'.

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