Q52 / 180 · NEET 2017 · Chemistry

A gas is allowed to expand in a well-insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy ΔU of the gas in joules will be

  • A
    1136.25 J.
  • B
    -500 J.
  • Correct answer
    C
    -505 J.
  • D
    +505 J.

Solution

ΔU=q+w

For adiabatic process, q=0

∴      ΔU=w

=-P⋅ΔV

= -2.5 atm×4.5-2.5L

= -2.5×2 L-atm

= -5×101.3 J

=-506.5 J

≈-505 J

Hence, the correct answer is option: 'C'.

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