Q37 / 180 · COMEDK 2021 · Chemistry

Why do alcohols and carboxylic acids have higher boiling points as compared to aldehydes?

  • A
    Due to-CHO group
  • B
    Due to Fazan's rule
  • Correct answer
    C
    Due to inter molecular hydrogen bonding
  • D
    Due to intramolecular hydrogen bonding

Solution

Alcohols (R-OH) and carboxylic acids (R-COOH) possess a hydrogen atom directly bonded to a highly electronegative oxygen atom. This structural feature allows them to form strong intermolecular hydrogen bonds between their molecules. Aldehydes (R-CHO), while polar, lack this O-H bond and can only form weaker dipole-dipole interactions with each other. Because intermolecular hydrogen bonds are significantly stronger than dipole-dipole interactions, much more energy (a higher temperature) is required to overcome these forces and separate the molecules into the gas phase. Consequently, alcohols and carboxylic acids have higher boiling points than aldehydes of comparable molecular mass. The correct option is (3).

Hence, the correct answer is option: 'C'.

More Chemical Bonding and Molecular Structure Questions