Q33 / 150 · MHT CET 2023 (10 May Shift 1) · Chemistry
Which of the following solutions exhibits lowest value of boiling point elevation assuming complete dissociation?
- A$0.1 \mathrm{~m} \mathrm{AlCl}_3$
- Correct answerB$0.01 \mathrm{~m} \mathrm{MgCl}_2$
- C$1 \mathrm{~m} \mathrm{KCl}$
- D$0.5 \mathrm{~m} \mathrm{NaCl}$
Solution
\begin{array}{|l|l|c|}
\hline & \multicolumn{1}{|c|}{ Solution } & \begin{array}{c}
Moles of particles in \\
\mathbf{1} \mathbf{~ k g ~ s o l u t i o n ~}
\end{array} \\
\hline (A) & 0.1 \mathrm{~m} \mathrm{AlCl}_3 & 0.4 \\
\hline (B) & 0.01 \mathrm{~m} \mathrm{AlCl}_2 & 0.03 \\
\hline (C) & 1 \mathrm{~m} \mathrm{KCl} & 2 \\
\hline (D) & 0.5 \mathrm{~m} \mathrm{NaCl} & 1 \\
\hline
\end{array}
$0.01 \mathrm{~m} \mathrm{MgCl}_2$ solution has minimum number of particles in solution, so it shows the lowest value of boiling point elevation.
Hence, the correct answer is option: 'B'.