Q5 / 150 · MHT CET 2022 (05 Aug Shift 1) · Chemistry
Which of the following reactions does not match correctly with its name?
- A$\mathrm{R}-\mathrm{NH}_2+3 \mathrm{R}-\mathrm{X} \rightarrow$ Hofmann exhaustive alkylation
- B$\mathrm{R}-\mathrm{CO}-\mathrm{NH}_2+\mathrm{Br}_2+4 \mathrm{KOH} \rightarrow:$ Hofmann degradation
- Correct answerC$\mathrm{R}-\mathrm{CO}-\mathrm{NH}_2+4[\mathrm{H}] \stackrel{\mathrm{LiA1H}_4}{\longrightarrow}:$ Mendius reduction
- D$\mathrm{R}-\mathrm{CH}_2-\stackrel{\oplus}{\mathrm{N}}-(\mathrm{R})_3 \stackrel{\oplus}{\mathrm{X}} \frac{(\mathrm{i}) \text { moist } \mathrm{Ag}_2{ }^0}{\stackrel{(\text { (ii })}{\longrightarrow},-\mathrm{H}_2{ }^0}$ : Hofmann elimination
Solution
Mendius reduction (Incorrect)
By using $\mathrm{Na} / \mathrm{EtOH}$, it is known as Mendius reduction.Hence, the correct answer is option: 'C'.