Q56 / 180 · NEET 2013 (All India) · Chemistry
Which of the following is paramagnetic?
- A$\mathrm{CO}$
- Correct answerB$\mathrm{O}_2^{-}$
- C$\mathrm{CN}^{-}$
- D$\mathrm{NO}^{+}$
Solution
Paramagnetic species contains unpaired electrons in their molecular orbital electronic configuration.
Molecular orbital configuration of the given species is as
$$
\begin{aligned}
& \mathrm{CO}(6+8=14)=\sigma 1 s^2, \stackrel{*}{\sigma} 1 s^2, \\
& \sigma 2 s^2, \stackrel{*}{\sigma} 2 s^2, \pi 2 p_x^2 \approx \pi 2 p_y^2, \sigma 2 p_z^2
\end{aligned}
$$
(All the electrons are paired so it is diamagneitc.)
$$
\begin{aligned}
& \mathrm{O}_2^{-}(8+8+1=17) \\
& =\sigma 1 s^2, \stackrel{*}{\sigma} 1 s^2, \sigma 2 s^2, \stackrel{*}{\sigma} 2 s^2, \sigma 2 p_z^2, \pi 2 p_x^2 \\
& \approx \pi 2 p_y^2, \stackrel{*}{\pi} 2 p_x^2 \approx \stackrel{*}{\pi} 2 p_y^1
\end{aligned}
$$
It contains one unpaired electron so it is paramagnetic.
$$
\begin{aligned}
& \mathrm{CN}^{-}(6+7+1=14)=\text { same as } \mathrm{CO} \\
& \mathrm{NO}^{+}(7+8-1)=\text { same as } \mathrm{CO}
\end{aligned}
$$
Thus, among the given species only $\mathrm{O}_2^{-}$is paramagnetic.
Hence, the correct answer is option: 'B'.