Q65 / 180 · NEET 2018 · Chemistry

Which of the following carbocations is expected to be the most stable?

  • Correct answer
    A
    Figure
  • B
    Figure
  • C
    Figure
  • D
    Figure

Solution

NO2 is present at the ortho- and the para- position of a positive charge.

NO2 present at the meta-position of a positive charge is less stable due to the e- withdrawing effect of  -NO2 (-I effect of NO2) 

Figure

NO2  present at the ortho- and para- of positive charge (Less stable due to the e- withdrawing effect of -NO2 (-M effect.)

Figure

The positive charge is destabilized by the electron-withdrawing groups.
-M dominates -I effect. So, the carbocation which has -I group is more stable.

Hence, the correct answer is option: 'A'.

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