Q69 / 200 · NEET 2023 (Manipur) · Chemistry
Given below are two statements:
Statement I: In an organic compound, when inductive and electromeric effects operate in opposite directions, the inductive effect predominates.
Statement II: Hyperconjugation is observed in o-xylene.
In the light of the above statements, choose the correct answer from the options given below
- ABoth Statement I and Statement II are true.
- BBoth Statement I and Statement II are false.
- CStatement I is true but Statement II is false.
- Correct answerDStatement I is false but Statement II is true.
Solution
- In an organic compound when inductive and electromeric effects operate in opposite directions, the electromeric effect predominates.

In alkylarene, $s p^3$ hybridized $\mathrm{C}-\mathrm{H}$ bonds are present the carbon of which is directly bonded to $s p^2$ carbon atoms so, hyperconjugation effect is observed in o-xylene.

In alkylarene, $s p^3$ hybridized $\mathrm{C}-\mathrm{H}$ bonds are present the carbon of which is directly bonded to $s p^2$ carbon atoms so, hyperconjugation effect is observed in o-xylene.
Hence, the correct answer is option: 'D'.