Q24 / 90 · JEE Main 2022 (27 Jun Shift 2) · Chemistry

When 5 moles of He gas expand isothermally and reversibly at 300 K from 10 litre to 20 litre, the magnitude of the maximum work obtained is J. [nearest integer ] (Given : R=8.3 J K-1 mol-1 and log2=0.3010)

Correct answer: 8630

Solution

Work done in isothermal reversible process is calculated by the equation

W=-2.303nRTlogV2V1n=Number of molesT=Temperature=300KV2=Final volume=20 litresV1=Initial volume=10 litres   

W=-2.303×5×8.3×300log2010

=-8630.38 J

Hence, the correct answer is 8630.

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