Q26 / 160 · TS EAMCET 2020 (11 Sep Shift 2) · Chemistry

What is the unit for the zero order rate constant?

  • Correct answer
    A
    $\mathrm{L}^{-1} \mathrm{~mol} \mathrm{~s}^{-1}$
  • B
    $\mathrm{L} \mathrm{mol} \mathrm{s}^{-1}$
  • C
    $\mathrm{L} \mathrm{mol}^{-1} \mathrm{~s}^{-1}$
  • D
    $\mathrm{L}^2 \mathrm{~mol}^{-2} \mathrm{~s}^{-1}$

Solution

$\because$ Rate $(r)=$ rate constant $(k)$ [conc. $]^{\text {order }}$ $k=\frac{\text { rate }}{[\text { conc. }]^{\text {order }(=n)}}=\frac{\mathrm{mol} \mathrm{L}^{-1}}{\left[\mathrm{~mol} \mathrm{~L}^{-1}\right]^n}$ where, $n=$ order of reaction $\therefore \quad k=\mathrm{mol}^{1-n}, \mathrm{~L}^{n-1} \mathrm{~s}^{-1}$ For zero order $(n=0)$ $\therefore \quad k=\mathrm{mol} \mathrm{L}^{-1} \mathrm{~s}^{-1}$

Hence, the correct answer is option: 'A'.

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