Q21 / 160 · TS EAMCET 2023 (14 May Shift 1) · Chemistry
The rate law for the decomposition of hydrogen iodide is $-\frac{\mathrm{d}[\mathrm{HI}]}{\mathrm{dt}}=\mathrm{k}[\mathrm{HI}]^2$. The units of rate constant $\mathrm{k}$ are
- Correct answerA$\mathrm{L}_{\mathrm{mol}^{-1}} \mathrm{~s}^{-1}$
- B$\mathrm{L}^{-1} \mathrm{~mol} \mathrm{~s}^{-1}$
- C$\mathrm{L}^2 \mathrm{~mol}^{-2} \mathrm{~s}^{-1}$
- D$\mathrm{L}^{1 / 2} \mathrm{~mol}^{-1 / 2} \mathrm{~s}^{-1}$
Solution
From the rate law,
units $=\frac{\left(\mathrm{mol} \mathrm{L}^{-1} \mathrm{~s}^{-1}\right)}{\left(\mathrm{mol} \mathrm{L}^{-1}\right)^2}=\mathrm{L} \mathrm{mol}^{-1} \mathrm{~s}^{-1}$
Hence, the correct answer is option: 'A'.