Q59 / 180 · NEET 2013 (Karnataka) · Chemistry

What is the density of $\mathrm{N}_2$ at $227^{\circ} \mathrm{C}$ and $5.00 \mathrm{~atm}$ pressure? $\left(\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1}\right.$ $\left.\mathrm{mol}^{-1}\right)$

  • A
    $1.40 \mathrm{~g} / \mathrm{ml}$
  • B
    $2.81 \mathrm{~g} / \mathrm{ml}$
  • Correct answer
    C
    $3.41 \mathrm{~g} / \mathrm{ml}$
  • D
    $0.29 \mathrm{~g} / \mathrm{ml}$

Solution

$$ \begin{aligned} \mathrm{pV} & =n \mathrm{RT} \\ \mathrm{P} & =\frac{\mathrm{m}}{\mathrm{M}} \times \frac{\mathrm{RT}}{\mathrm{V}} \\ & =\frac{5 \times 28}{0.0821 \times 500}=3.41 \mathrm{~g} / \mathrm{mL} \end{aligned} $$

Hence, the correct answer is option: 'C'.

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