Q21 / 100 · BITSAT 2024 (Memory Based Paper 2) · Chemistry

What is $X$ in the following reaction? $\mathrm{CO}+2 \mathrm{H}_2 \xrightarrow{x} \mathrm{CH}_3 \mathrm{OH}$

  • A
    $623 \mathrm{~K} / 300 \mathrm{~atm}$
  • B
    $\mathrm{KMnO}_4 / \mathrm{H}^{\oplus}$
  • C
    $\mathrm{Zn} / \Delta$
  • Correct answer
    D
    $\mathrm{ZnO}-\mathrm{Cr}_2 \mathrm{O}_3, 200-300 \mathrm{~atm}, 573-673 \mathrm{~K}$

Solution

The given reaction is for the industrial preparation methanol from a mixture of carbon monoxide and hydrogen . In the reaction the gaseous mixture is subjected to 200 atmosphere and then passed over heated catalyst mixture of ZnO and $\mathrm{Cr}_2 \mathrm{O}_3$ kept at $573-673 \mathrm{~K}$. This reaction results the formation of methanol vopours which are then condensed to liquid state.

Hence, the correct answer is option: 'D'.

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