Q47 / 150 · MHT CET 2026 (18 April Shift 2) · Chemistry

What is EAN for metal ion in $[\text{Fe(CN)}_6]^{3-}$ ?

  • A
    $37$
  • B
    $36$
  • Correct answer
    C
    $35$
  • D
    $34$

Solution

The atomic number of iron (Fe) is $26$.

Let the oxidation state of Fe in $[\text{Fe(CN)}_6]^{3-}$ be $x$.

$x + 6(-1) = -3$

$x = +3$

The formula for Effective Atomic Number (EAN) is:

$\text{EAN} = Z - \text{Oxidation state} + 2 \times (\text{Coordination number})$

$\text{EAN} = 26 - 3 + 2 \times 6$

$\text{EAN} = 23 + 12 = 35$

Answer: $35$

Hence, the correct answer is option: 'C'.

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