Q140 / 160 · TS EAMCET 2019 (03 May Shift 1) · Physics

Two gases $A$ and $B$ are contained in two separate, but otherwise identical containers. Gas $A$ consists of monatomic molecules, each with atomic mass of $4 u$ whereas Gas $B$ consists of rigid diatomic molecules, each with atomic mass of $20 u$. If gas $A$ is kept at $27^{\circ} \mathrm{C}$, at what temperature should gas $B$ be kept so that both have the same rms speed?

  • A
    $27^{\circ} \mathrm{C}$
  • B
    $54^{\circ} \mathrm{C}$
  • Correct answer
    C
    $270^{\circ} \mathrm{C}$
  • D
    $62^{\circ} \mathrm{C}$

Solution

For monatomic gas $A$, atomic mass of molecules of gas $A, m_A=4 u$ and temperature of gas, $T_A=27^{\circ} \mathrm{C}$ For diatomic gas $B$, atomic mass of molecules of gas $B$, $m_B=2 \times 20 \mathrm{u}=40 \mathrm{u}$ Temperature of gas, $B=\mathrm{T}_B$ Since, $r m s$ speed of the molecules of gas, $A=\mathrm{rms}$ speed of molecules of gas, $B$ $$ \begin{aligned} \left(v_{\mathrm{rms}}\right)_A & =\left(v_{\mathrm{rms}}\right)_B \\ \Rightarrow \quad \sqrt{\frac{3 R T_A}{m_A}} & =\sqrt{\frac{3 R T_B}{m_B}} \\ \Rightarrow \quad \frac{\mathrm{T}_A}{m_A} & =\frac{\mathrm{T}_B}{m_B} \Rightarrow \frac{27}{4 u}=\frac{\mathrm{T}_B}{40 \mathrm{u}} \\ \mathrm{T}_B & =270^{\circ} \mathrm{C} \end{aligned} $$

Hence, the correct answer is option: 'C'.

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