Q138 / 160 · TS EAMCET 2024 (10 May Shift 2) · Physics

The temperature at which the rms speed of oxygen molecules is $75 \%$ of rms speed of nitrogen molecules at a temperature of $287^{\circ} \mathrm{C}$ is

  • Correct answer
    A
    $87^{\circ} \mathrm{C}$
  • B
    $127^{\circ} \mathrm{C}$
  • C
    $227^{\circ} \mathrm{C}$
  • D
    $360^{\circ} \mathrm{C}$

Solution

$R M S$ speed, $v_{\mathrm{rms}}=\sqrt{\frac{3 R T}{M}} \Rightarrow v_{\mathrm{rms}} \propto \sqrt{\frac{\mathrm{T}}{\mathrm{M}}}$ $\mathrm{v}_{\mathrm{rms}, \mathrm{o}}=75 \%$ of $\mathrm{v}_{\mathrm{rms}, \mathrm{N}}=\frac{3}{4} \mathrm{v}_{\mathrm{rms}, \mathrm{N}}$ $\therefore \frac{\mathrm{v}_{\mathrm{rms}, \mathrm{O}}}{\mathrm{v}_{\mathrm{rms}, \mathrm{N}}}=\sqrt{\frac{\mathrm{T}_{0}}{\mathrm{T}_{\mathrm{N}}} \times \frac{\mathrm{M}_{\mathrm{N}}}{\mathrm{M}_{\mathrm{o}}}}=\sqrt{\frac{\mathrm{T}_{\mathrm{c}}}{(273+287)} \times \frac{28}{32}}$ $\Rightarrow\left(\frac{3}{4}\right)^2=\frac{T_0}{20 \times 32} \Rightarrow T_0=360 \mathrm{~K}=(360-273)^{\circ} \mathrm{C}$ $=87^{\circ} \mathrm{C}$

Hence, the correct answer is option: 'A'.

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