Q9 / 90 · JEE Main 2021 (27 Jul Shift 2) · Chemistry

To an aqueous solution containing ions such as Al3+,Zn2+,Ca2+,Fe3+,Ni2+,Ba2+ and Cu2+ was added conc. HCl, followed by H2S. The total number of cations precipitated during this reaction is/are :

  • Correct answer
    A
    1
  • B
    3
  • C
    4
  • D
    2

Solution

Al3+ and Fe3+ sulphides hydrolyse in water. Ni2+ and Zn2+ require basic medium with H2 S to form precipitate.  Ca2+ and Ba2+ sulphides are also soluble.  only Cu2+ can form the precipitate with H2S in the acidic medium.

Hence, the correct answer is option: 'A'.

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