Q35 / 97 · NTA Abhyas (JEE Main) 2020 · Chemistry · Solutions

The vapor pressure of benzene is 53.3 kPa at 603 oC, but it falls to 51.5  kP a when 19 g of a non-volatile organic compound is dissolved in 500 g benzene. The molar mass of the non-volatile compound is

  • A
    82
  • Correct answer
    B
    85
  • C
    88
  • D
    92

Solution

P 0  = 53.3 kPa
P s =51.5  kP a
P0-PsPs=nN=19×78M×500
53.3-51.551.5=nN=19×78M×500
M=19×78×51.5(53.3-51.5)×500
M=85 g

Hence, the correct answer is option: 'B'.

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