Q20 / 150 · MHT CET 2026 (18 April Shift 1) · Chemistry

The solubility of a sparingly soluble a salt $\text{AB}_2$ is $1 \times 10^{-6}\ \text{mol/dm}^3$. Calculate its solubility product?

  • A
    $1 \times 10^{-12}$
  • B
    $2 \times 10^{-12}$
  • C
    $3 \times 10^{-12}$
  • Correct answer
    D
    $4 \times 10^{-18}$

Solution

The dissociation of the salt $AB_2$ is given by:

$AB_2 \rightleftharpoons A^{2+} + 2B^-$

Let the solubility of the salt be $S$. The equilibrium concentrations are:

$[A^{2+}] = S$

$[B^-] = 2S$

The solubility product $K_{sp}$ is:

$K_{sp} = [A^{2+}][B^-]^2$

$K_{sp} = (S)(2S)^2 = 4S^3$

Given $S = 1 \times 10^{-6}\ \text{mol/dm}^3$, substituting this value:

$K_{sp} = 4(1 \times 10^{-6})^3$

$K_{sp} = 4 \times 10^{-18}$

Answer: $4 \times 10^{-18}$

Hence, the correct answer is option: 'D'.

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