Q29 / 180 · KCET 2012 · Chemistry

The relative acidic strengths of benzoic acid, $o$-toluic acid and $p$-toluic acid is of the decreasing order

  • A
    $o$-toluic acid $>p$-toluic acid $>$ benzoic acid
  • B
    $p$-toluic acid $>$ benzoic acid $>0$-toluic acid
  • Correct answer
    C
    0 -toluic acid $>$ benzoic acid $>p$-toluic acid
  • D
    $p$-toluic acid $>0$-toluic acid $>$ benzoic acid

Solution

+ I effect showing groups like $\mathrm{CH}_{3}$ when present decreases the acidic strength of carboxylic acids but ortho toluic acid is more acidic due to ortho effect.
Figure

Hence, the correct answer is option: 'C'.

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