Q29 / 180 · KCET 2012 · Chemistry
The relative acidic strengths of benzoic acid, $o$-toluic acid and $p$-toluic acid is of the decreasing order
- A$o$-toluic acid $>p$-toluic acid $>$ benzoic acid
- B$p$-toluic acid $>$ benzoic acid $>0$-toluic acid
- Correct answerC0 -toluic acid $>$ benzoic acid $>p$-toluic acid
- D$p$-toluic acid $>0$-toluic acid $>$ benzoic acid
Solution
+ I effect showing groups like $\mathrm{CH}_{3}$ when present decreases the acidic strength of carboxylic acids but ortho toluic acid is more acidic due to ortho effect.


Hence, the correct answer is option: 'C'.