Q28 / 180 · KCET 2012 · Chemistry

Benzylamine is a stronger base than aniline because

  • Correct answer
    A
    the lone pair of electrons on the nitrogen atom in aniline is delocalised
  • B
    the lone pair of electrons on the nitrogen atom in aniline is not involved in resonance
  • C
    benzylamine has a higher molecular mass than aniline
  • D
    the lone pair of electrons on the nitrogen atom in benzylamine is delocalised

Solution

Benzyloamine $\Rightarrow$
Figure

Figure
Due to delocalisation of lone pair of electrons on the nitrogen atom in aniline, it is weaker basic than benzaldehyde.

Hence, the correct answer is option: 'A'.

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