Q15 / 180 · COMEDK 2018 · Chemistry

The reaction $\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{ONa}+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{I} \longrightarrow$ $\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OC}_{2} \mathrm{H}_{5}+\mathrm{NaI}$ is known as

  • A
    Kolbe's synthesis
  • B
    Wurtz's synthesis
  • Correct answer
    C
    Williamson's synthesis
  • D
    Grignard's synthesis

Solution

Williamson ether synthesis is an organic reaction, forming an ether from alkyl halide and deprotonated alcohol i.e. $\mathrm{CiH}_{2} \mathrm{ONa}+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{I} \longrightarrow \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OC}_{2} \mathrm{H}_{5}+\mathrm{NaI}$ Sodium ethoxide+Ethane iodide $\longrightarrow$ Ethoxycthane (ester)

Hence, the correct answer is option: 'C'.

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