Q16 / 180 · COMEDK 2018 · Chemistry

$\Delta G^{\circ} v s \dddot{l}$ plot in the Eliingham's diagram, slopes downwards for the reaction

  • A
    $\mathrm{Mg}+\frac{1}{2} \mathrm{O}_{2} \longrightarrow \mathrm{MgO}$
  • B
    $2 \mathrm{Ag}+\frac{1}{2} \mathrm{O}_{2} \longrightarrow \mathrm{Ag}_{2} \mathrm{O}$
  • Correct answer
    C
    $\mathrm{C}+\frac{1}{2} \mathrm{O}_{2} \longrightarrow \mathrm{CO}$
  • D
    $\mathrm{CO}+\frac{1}{2} \mathrm{O}_{2} \longrightarrow \mathrm{CO}_{2}$

Solution

For the reaction, $\mathrm{C}+\frac{1}{2} \mathrm{O}_{2} \longrightarrow \mathrm{CO}$, $\Delta G^{\circ}$ vs $T$ plot in the Ellingham's diagram slopes downwards. As for this reaction $\Delta G^{\circ}$ become more negative with increase in temperature.

Hence, the correct answer is option: 'C'.

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