Q27 / 90 · KVPY 2016 (SB/SX) · Chemistry

The ratio of root mean square velocity of hydrogen at $50 \mathrm{~K}$ to that of nitrogen at $500 \mathrm{~K}$ is closest to

  • Correct answer
    A
    $1.18$
  • B
    $0.85$
  • C
    $0.59$
  • D
    $1.40$

Solution

$\mathrm{V}_{\mathrm{rms}}=\sqrt{\frac{3 \mathrm{RT}}{\mathrm{M}}}$ $\frac{\left(\mathrm{V}_{\mathrm{rms}}\right)_{\mathrm{H}_{2}}}{\left(\mathrm{~V}_{\mathrm{rms}}\right)_{\mathrm{O}_{2}}}=\frac{\sqrt{\frac{3 \times \mathrm{R} \times 50}{2}}}{\sqrt{\frac{3 \times \mathrm{R} \times 500}{28}}}=1.18$

Hence, the correct answer is option: 'A'.

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