Q1 / 75 · JEE Main 2026 (02 April Shift 2) · Chemistry
The ratio of mass percentage (w/w) of C : H in a hydrocarbon is $12 : 1$. It has two carbon atoms. The weight (in g) of $CO_2(g)$ formed when $3.38$ g of this hydrocarbon is completely burnt in oxygen is : (Given : Molar mass in g mol$^{-1}$ C : 12, H : 1, O : 16)
- A$5.68$
- Correct answerB$11.44$
- C$22.74$
- D$17.05$
Solution
Ratio of mass percentage of C : H = $12 : 1$
Ratio of moles of C : H = $\dfrac{12}{12} : \dfrac{1}{1} = 1 : 1$
The empirical formula is $CH$. Since the hydrocarbon has two carbon atoms, its molecular formula is $C_2H_2$.
Molar mass of $C_2H_2 = 2 \times 12 + 2 \times 1 = 26$ g mol$^{-1}$
Moles of $C_2H_2$ in $3.38$ g = $\dfrac{3.38}{26} = 0.13$ mol
The combustion reaction is:
$C_2H_2 + \dfrac{5}{2}O_2 \rightarrow 2CO_2 + H_2O$
From the stoichiometry, $1$ mole of $C_2H_2$ produces $2$ moles of $CO_2$.
Moles of $CO_2$ produced = $2 \times 0.13 = 0.26$ mol
Molar mass of $CO_2 = 12 + 2 \times 16 = 44$ g mol$^{-1}$
Weight of $CO_2$ formed = $0.26 \times 44 = 11.44$ g
Answer: $11.44$
Ratio of moles of C : H = $\dfrac{12}{12} : \dfrac{1}{1} = 1 : 1$
The empirical formula is $CH$. Since the hydrocarbon has two carbon atoms, its molecular formula is $C_2H_2$.
Molar mass of $C_2H_2 = 2 \times 12 + 2 \times 1 = 26$ g mol$^{-1}$
Moles of $C_2H_2$ in $3.38$ g = $\dfrac{3.38}{26} = 0.13$ mol
The combustion reaction is:
$C_2H_2 + \dfrac{5}{2}O_2 \rightarrow 2CO_2 + H_2O$
From the stoichiometry, $1$ mole of $C_2H_2$ produces $2$ moles of $CO_2$.
Moles of $CO_2$ produced = $2 \times 0.13 = 0.26$ mol
Molar mass of $CO_2 = 12 + 2 \times 16 = 44$ g mol$^{-1}$
Weight of $CO_2$ formed = $0.26 \times 44 = 11.44$ g
Answer: $11.44$
Hence, the correct answer is option: 'B'.